Good curing, enabling prolonged hydration and the development of a well-developed microstructure, is imperative if concrete is to perform at its full potential. This may become more important with the increasing use of composite cements containing more slowly reacting additions. Furthermore, the effects of improper curing, i.e. compromised durability, may not become visible for many years. A series of concrete mixes have been prepared of 20 or 50 MPa target mean strength, using either CEM I or CEM I + 30% fly ash as the binder. Mixes were designed with two different workabilities, (10-30 and 60-180 mm slump) Samples were cured in a fog room at 20 ± 30C and 99 ± 1% RH or under ambient conditions 20 ± 30C and 42 ± 5% RH. Performance was evaluated in terms of compressive strength, transport properties and resistance to carbonation. Equivalent paste samples were characterised by TGA, XRD and SEM to follow hydration and microstructural development. Improper curing did not greatly affect compressive strength. However, the effects on transport properties, and therefore properties that may affect durability, were more profound. The effects of non-ideal curing were greater for lower strength mixes, those containing fly ash and, to a less extent, less workable mixes.
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机译:如果混凝土要发挥其全部潜能,必须进行良好的固化,使其能够长期水化并形成发达的微观结构。随着越来越多地使用反应速度较慢的复合水泥的使用,这可能变得更加重要。此外,不适当固化的效果,即耐久性的降低,可能很多年后才变得可见。使用CEM I或CEM I + 30%粉煤灰作为粘结剂,已制备了一系列目标平均强度为20或50 MPa的混凝土混合物。设计出具有两种不同加工性的混合物(10-30和60-180 mm坍落度)。将样品在雾化室中于20±30C和99±1%RH或在环境条件20±30C和42±5%RH下固化。根据抗压强度,运输性能和抗碳化性评估性能。通过TGA,XRD和SEM对等效的糊状样品进行表征,以跟踪水合和微观结构的发展。固化不当不会显着影响抗压强度。但是,对运输性能的影响以及因此可能影响耐久性的性能的影响更为明显。对于低强度的混合物,含有粉煤灰的混合物,以及程度较差的可加工混合物,非理想固化的影响更大。
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